The Study of CO2 Fixation on The Magnesium-Lithium Mixed Metal Complexes
The reaction of Mg(NPh2)2 with LiNR2 (R= SiMe3, NiPr, NiBu) generated the same product, [Mg(NPh2)3(THF)][Li(THF)4] which was identified by 1H-NMR and X-ray crystallography. The magnesium-lithium mixed metal complex reacted with excess carbon dioxide in the ice bath to generate the tetralithium complex, Li4(O2CNPh2)4(THF)4 which was identified by 1H-NMR, 13C-NMR, IR, and X-ray crystallography.
Advisor:Chung-Cheng Chang; none; none; none
School:National Sun Yat-Sen University
School Location:China - Taiwan
Source Type:Master's Thesis
Keywords:co2 fixation mixed metal complexes
Date of Publication:08/18/2003