The Study of CO2 Fixation on The Magnesium-Lithium Mixed Metal Complexes

by Chen, Shin-Yi

Abstract (Summary)
The reaction of Mg(NPh2)2 with LiNR2 (R= SiMe3, NiPr, NiBu) generated the same product, [Mg(NPh2)3(THF)][Li(THF)4] which was identified by 1H-NMR and X-ray crystallography. The magnesium-lithium mixed metal complex reacted with excess carbon dioxide in the ice bath to generate the tetralithium complex, Li4(O2CNPh2)4(THF)4 which was identified by 1H-NMR, 13C-NMR, IR, and X-ray crystallography.
Bibliographical Information:

Advisor:Chung-Cheng Chang; none; none; none

School:National Sun Yat-Sen University

School Location:China - Taiwan

Source Type:Master's Thesis

Keywords:co2 fixation mixed metal complexes


Date of Publication:08/18/2003

© 2009 All Rights Reserved.