SMILETRAP I / II :Precision Improvements in Penning-Trap Mass-Spectrometry
This thesis describes the final precision mass measurements with SMILETRAP I, where a relative precision of < 1 ppb (10-9) was reached routinely, and the development of SMILETRAP II, aiming for measurements with < 0.1 ppb relative precision. The emphasis of the thesis is on the implementation of new techniques for achieving this precision improvement with SMILETRAP II. The Ramsey multiple-pulse excitation technique was tested at SMILETRAP I, and a reduction of the statistical uncertainty by factor three could by verified. The technique was applied in the last measurement with SMILETRAP I on H2+ and D+ ions. From these measurements the proton mass was deduced with a relative error of 0.18 ppb. It was found that temperature dependent magnetic field oscillations limited us from reducing the uncertainties further. A technical achievement of reducing the peak to peak temperature oscillation in the trapping region of SMILETRAP II by a factor four is presented, which should give an extended observation time and likewise improved precision. The new SMILETRAP II super-conducting magnet, with a slightly stronger field of 5.8 T compared with the previous of 4.7 T, was installed and adjusted. A careful field alignment and reduction of inhomogeneities was done for minimizing the disturbances of the cyclotron frequency for improved precision. In that attempt, the localization and control of the trapped ion motion is also important. Thus a new cooling trap was set up. In the spring of 2009 coherent axial motion of a confined ion cloud was discovered in the cooling trap. By observation of the axial oscillations we can see the effects of evaporative cooling in the reduction of the axial energy distribution. Storing the ions up to 1 s in the cooling trap reduces the energy distribution by a factor of five. Other remarkable results of the ion oscillations are also reported.
Source Type:Doctoral Dissertation
Keywords:NATURAL SCIENCES; Physics; Atomic and molecular physics; Atomic physics; Penning trap; Mass spectrometers; Instrumentation and methods for time-of-flight (TOF) spectroscopy; Highly charged ions; fysik; Physics
Date of Publication:01/01/2009