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Laboratory investigation of chemical and physical properties of soot-containing aerosols [electronic resource] /

by Zhang, Dan

Abstract (Summary)
Soot particles released from fossil fuel combustion and biomass burning have a large impact on the regional/global climate by altering the atmospheric radiativeproperties and by serving as cloud condensation nuclei (CCN). However, the exact forcing is affected by the mixing of soot with other aerosol constituents, such as sulfuric acid. In this work, experimental studies have been carried out focusing on three integral parts: (1) heterogeneous uptake of sulfuric acid on soot; (2) hygroscopic growth of H?SO?-coated soot aerosols; (3) effect of H?SO? coating on scattering and extinction properties of soot particles. A low-pressure laminar-flow reactor, coupled to ion drift chemical ionization mass spectrometry (ID-CIMS) detection, is used to study uptake coefficients of H?SO? on combustion soot. The results suggest that uptake of H?SO? takes place efficiently on soot particles, representing an important route to convert hydrophobic soot to hydrophilic aerosols. A tandem differential mobility analyzing (TDMA) system is employed to determine the hygroscopicity of freshly generated soot in the presence of H?SO? coating. It is found that fresh soot particles are highly hydrophobic, while coating of H?SO? significantly facilitates water uptake on soot even at sub-saturation relative humidities. The results indicate that aged soot particles in the atmosphere can potentially be an efficient source of CCN. Scattering and extinction coefficient measurements of the soot-H?SO? mixed particles are conducted using a three wave length Nephelometer and a multi-path extinction cell. Coating of H?SO? is found to increase the single scattering albedo (SSA) of soot particles which has impact on the aerosol direct radiative effect. Other laboratory techniques such as transmission electron microscopy (TEM) and Fourier transform infrared spectrometry (FTIR) are utilized to examine the morphology and chemical composition of the soot-H?SO? particles. This work provides critical information concerning the heterogeneous interaction of soot and sulfuric acid, and how their mixing affects the hygroscopic and optical properties of soot. The results will improve our ability to model and assess the soot direct and indirect forcing and hence enhance our understanding of the impact of anthropogenic activities on the climate.
Bibliographical Information:

Advisor:

School:Texas A&M International University

School Location:USA - Texas

Source Type:Master's Thesis

Keywords:major atmospheric sciences soot optical hygroscopicity uptake aerosol

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